CB is indeed 26-27MHz so is in a different band as you say. CB's work at best a few K's in the bush. OK for truck to truck comms on the trail, as long as they are very close.
If you use a HAM radio you can get much more than this using simplex (radio to radio), i've used mine truck to truck to around 30K's, and if you use repeaters you can talk 50Kms + and even all over the world using something like IRLP which links repeaters via the net. And with satellite you can talk thousands of miles. There is so much more to HAM than CB.
But CB is simple to operate, you have 40 channels and that's it. With HAM you need a license, use a callsign, know what frequency to use, know the duplex setting, tone settings etc etc and because there are so many frequencies and modes you really need to understand how it all works to get the most out of it (i.e. take a course). You can't just switch in on and talk like you can with CB.
If you get your basic HAM license you can use for example :-
The 2 Meter HAM band is VHF at 144-148MHz
The 70cm HAM band is UHF at 430-450MHz
If you get your basic plus, you get access to HF which is 50MHz and below.
If pass the advanced test you can build your own gear.
Try and meet up with someone with a HAM radio and get the basics, then take a course!